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29 Cards in this Set

  • Front
  • Back

Monomer (Building Block)

~ Small unit molecule joined with others to form polymer


~ Ex) Amino acids, simple sugars, fatty acids, nucleotides

Polymer

~ Large molecule which consists of repeating units or monomers


~ Ex) Proteins, Starch, Neutral Fat, DNA/RNA

Macromolecule

~ A large molecule


~ Ex) Neutral fat, RNA/DNA

Macromolecules: Organic Compounds

~ Contain C & H


~ Important biological molecules


~ Formed in dehydration synthesis reactions

Dehydration Synthesis Reactions

~ Type of chemical reaction which occurs in cells


- Small molecules (monomers) are joined to form large molecules (polymers)


- Water is released in the process


~ The water molecule forms from a hydroxyl (-OH) group from the end of one molecule and a hydrogen atom from the end of the second molecule. Water is released in the process and a covalent (peptide) bond forms between the two monomers.


~ Dehydration synthesis reactions result in the formation of proteins, lipids, carbohydrates, and nucleic acids


- Specific enzymes are needed to catalyze each type of dehydration synthesis reaction

Hydrolysis Reactions

~ Reverse reactions of dehydration synthesis


- Large molecules (polymers) are broken down into the molecules (monomers) of which they are composed


- The addition of water leads to a disruption of the chemical bonds linking molecules together


~ The hydroxyl group from the water attaches to one side of the chemical bond and the hydrogen of water attaches to the other side


- This breaks the bond between the two monomers


~ Hydrolysis reactions result in the breakdown of proteins, lipids, carbohydrates and nucleic acids


- Specific enzymes are needed to catalyze each type of hydrolysis reaction



Carbohydrates

~ Characterized by the empirical formula (CH20)


~ Hydrates of carbon


- due to the ratio of hydrogen to oxygen within any carbohydrate molecule (2H: 1O)


~ Carbohydrates contain only carbon, oxygen,and hydrogen

Carbohydrates: Types Of Carbohydrates and Functions

~ Primary function: Energy Source


~ Monosaccarides, Disaccharides,Polysaccharides



Carbohydrates: Types Of Carbohydrates: Monosaccharides

~ Structure


- One sugar unit (monomer)


- Small number of carbon atoms (3-7C)


- Carbons may be organized linearly or in a ring


~ Examples


- 5 Carbon Sugars (pentose sugars): ribose and deoxyribose


- structural components of nucleic acids (RNA/ DNA)


- 6 Carbon Sugars (hexose sugars): glucose, fructose and galactose


~ Functions:


- Primary energy source for cells (especially glucose)


- Monomers for disaccarides and polysaccarides


~ The most common monosaccharide is glucose

Carbohydrates: Types Of Carbohydrates: Disaccharides

~ Structure:


- consist of two monosaccharides covalently bonded through dehydration synthesis


- weak bond called "glycosidic or ester linkage"


- these bonds are broken without using too much energy


- primary function: energy storage


- only monosaccharides can be directly used by organisms for energy (must first be broken down to their monomers before they can be used for energy by a cell)


~ Examples: Maltose, Sucrose, Lactose

Carbohydrates: Types Of Carbohydrates: Disaccharides: Maltose

~ Formed when two glucose molecules combine


~ Function:


- Energy storage

Carbohydrates: Types Of Carbohydrates: Disaccharides: Sucrose

~ Formed when one glucose molecules combines with one fructose molecule


~ Function:


- Energy storage in plants and energy transport in plants


- Sugars made in the leaves of green plants are transported to non photosynthetic regions for storage in the form of sucrose

Carbohydrates: Types Of Carbohydrates: Disaccharides: Lactose

~ Formed when one lactose molecule combines with one galactose molecule


~ Function:


- Energy storage

Carbohydrates: Types Of Carbohydrates: Polysaccharides

~ Structure:


- consist of many (3 or more) monosaccharides which are linked together through dehydration synthesis


- polysaccharides are fairly large molecules (macromolecules) and consist of many repeating units (monomers) and are described as polymers


~ Types: Starch (amylose), Glycogen, Cellulose,Chitin


~ Other Functions: Chains of carbohydrates are attached to the outside of the cell membrane. carbohydrates are attached to either proteins (glycoproteins) or fats (glycolipids)


- Carbohydrate chain function in


- cell-cell recognition: acts as a marker so the immune system recognizes the cell


- form receptor sites for specific molecules to attach to allow communication between cells


ie. protein hormones attach to specific receptor sites on the outside of their target cells

Carbohydrates: Types Of Carbohydrates: Polysaccharides: Starch (Amylose)

~ Structure


- polymer of glucose


- consists of a relatively straight chain of glucose molecules with few side branches


- glucose monomers in starch are joined by alpha 1-4 bonds (glycosidic bonds) formed in the process of dehydration synthesis


- found in plants


~ Function:


- energy storage in plants

Carbohydrates: Types Of Carbohydrates: Polysaccharides: Glycogen

~ Structure:


- Hexagonal


- polymer of glucose


- consists of highly branched chain of glucose molecules


- glucose monomers in glycogen are joined by alpha 1-4 bonds (glycosidic bonds) formed in the process of dehydration synthesis


- found in animals


~ Function:


- short term energy storage in animals (stored in the muscles and liver)



Carbohydrates: Types Of Carbohydrates: Polysaccharides: Cellulose

~ Structure:


- polymer of glucose


- straight/ linear chain of glucose molecules (no branching straight chains form cellulose fibres)


- glucose monomers in cellulose are joined by beta 1-4 bonds (glycosidic bonds) formed in the process of dehydration synthesis


- found in plants


~ Function:


- important structural component in plant cell walls. The presence of cellulose within the cell wall provides the plant cell with strength and support

Carbohydrates: Types Of Carbohydrates: Polysaccharides: Chitin

~ Structure:


- polymer of glucose


- structure similar to cellulose, glucose monomers are joined by beta 1-4 bonds


- unique as this polysaccharide contains nitrogen*


- combines with calcium carbonate to form strong structural compound


~ Function:


- used make exoskeleton in arthropods and cell walls in fungi

Lipids

~ Organic molecules which consist primarily of carbon, hydrogen, and oxygen atoms. Some contain small amounts of phosphorous and nitrogen


~ the ratio of H+ to O is higher, therefore insoluble in water


~ Three types: Neutral fats, phospholipids, and steroids

Lipids: Types Of Lipids: Neutral Fats (Triglycerides)

~ Nonpolar; water insoluble


~ Structure:


- consist of one molecule of glycerol and three fatty acids


- Fatty acids consist of a long hydrocarbon chain ending in a -COOH group (carboxylic acid)


- In cells, most fatty acids contain between 16-18 carbon atoms


~ Triglycerides are formed by 3 dehydration synthesis reactions; three fatty acid molecules combine with 1 glycerol molecule to form a triglyceride or neutral fat


~ Functions:


- Serve as long term energy storage in animals


- insulation for animals living in colder regions

Lipids: Types Of Lipids: Neutral Fats (Triglycerides): Saturated Fats

~ Consist of saturated fatty acids


~ Typically solid at room temperature


~ Derived from animal sources


- Eg) butter, animal fats


~ Contain the maximum possible number of hydrogen atoms


~ No double bonds between the carbon atoms and hydrocarbon chain


~ Lack of a double bond produces a relatively straight molecule


~ As a result, saturated fatty acids tend to be packed tightly together



Lipids: Types Of Lipids: Neutral Fats (Triglycerides): Unsaturated Fats

~ Consist of unsaturated fatty acids


~ Typically liquids are room temperature


~ Derived from plant sources


-Eg) oils (vegetable, etc)


~ Contain less than the maximum possible number of hydrogen atoms


~ Double bonds occur between the carbon in the hydrocarbon chain wherever there are fewer than two hydrogen atoms per carbon atom


~ Presence of double bond produce a bent molecule


~ As a result, unsaturated fatty acids are not packed tightly together

Lipids: Types Of Lipids: Phospholipids (Structure)

~ Structure:


- Similar to neutral fats


- Consist of one glycerol molecule joined to 2 fatty acids; the third fatty acid is replaced by a phosphate group


- The phosphate group is in turn, often attached to a nitrogen containing group


- The fatty acids and phosphate groups are attached to the glycerol molecule by 3 dehydration synthesis reactions


- Have both a polar and non polar region


- The phosphate end of the phospholipid can ionize and therefore is polar and soluble in water (the phosphate head)

Hydrophilic

A type of molecule that interacts with water by dissolving in water and/or forming hydrogen bonds

Hydrophobic

A type of molecule that does not interact with water; insoluble, non polar

Lipids: Types Of Lipids: Phospholipids (Functions)

~ Major structural component of the cell membrane


~ Arrange themselves into a phospholipid bilayer in the presence of water


- The polar phosphate heads face outward in contact with the watery cytoplasm or extracellular fluid. The nonpolar fatty acids face inward avoiding contact with water.

Lipids: Types Of Lipids: Steroids

~ Structure


- Very different from other fats


- 4 fused carbon rights ( 3 six carbon rings and one 5 carbon ring)


- Different steroids have different functional groups attached to them


- Position of double bonds within the rings of the steroid may vary


~ Function


- Cholesterol is used to make other steroids


- Cholesterol helps stabilize the cell membrane


- The sex hormones: testosterone, estrogen and progesterone, are steroid hormones that all have effects on sexual characteristics and reproduction


- Aldosterone is a steroid hormone which helps control blood sodium levels and blood pressure


- Cortisol is a steroid hormone which helps in the recovery from physical injury and reduces the inflammatory response

Functional Group

A characteristic arrangement of atoms within a molecule that determine the important chemical and physical properties of the compound

Hormone

A chemical messenger responsible for controlling specific body functions