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106 Cards in this Set

  • Front
  • Back

Acid

A substance that releases hydrogen ions in aqueous solution (a proton donor)

Alkali

A base that is soluble in water and releases hydroxide ions in aqueous solution

Anhydrous Salt

A salt that doesn't contain any water of crystallisation.

Atom

A neutral particle made up of protons and neutrons in a central nucleus, and electrons orbiting the nucleus.

Atom economy

The proportion of reactant atoms that become a part of the desired product, expressed as a percentage.

Atomic (proton) number

The number of protons in the nucleus.

Atomic Radius

The distance between the nucleus of an atom and it's outermost electrons.

Average bond enthalpy

The energy needed to break one mole of a bond in the gas phase, averaged over the different compounds that the bond is found in.

Avogadro constant

The number of particles in one mole of substance; 6.02 x 10^23

Balanced Equation

An equation that has the same number of each type of atom and the same overall charge on each side.

Base

A substance that removes hydrogen ions from an aqueous solution (a proton acceptor)

Bohr model

A model for the structure of an atom proposed by Niels Bohr. He suggested that electrons only exist in fixed orbitals (shells) and not anywhere else.

Bond enthalpy

The energy required to break a bond between two atoms. Usually given as an 'average bond enthalpy' (an average value for the particular bond over the range of compounds it is found in)

Bond Fission

The process of breaking a covalent bond

Concentration

A measure of how many moles (or grams) of a substance are dissolved in a volume of solution.

Coordinate (dative covalent) bond

A covalent bond formed when one atom provides both of the shared electrons.

Covalent bond

The strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.

Covalent bond

The strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.

Delocalised electron

An electron that is not attached to a specific atom.

Dipole

A difference in charge between two atoms caused by a shift in the electron density in a bond.

Displacement reaction

A reaction where a more reactive element pushes out (displaces) a less reactive element in an ionic solution.

Displayed formula

A way of representing a molecule that shows how all the atoms are arranged and all the bonds between them.

Displayed formula

A way of representing a molecule that shows how all the atoms are arranged and all the bonds between them.

Disproportionation

When an element is both oxidised and reduced in a single chemical reaction.

Electron

A subatomic particle with a relative charge of 1- and a relative mass of 1/2000, located in the orbitals around the nucleus.

Electron

A subatomic particle with a relative charge of 1- and a relative mass of 1/2000, located in the orbitals around the nucleus.

Electron configuration

The number of electrons that an atom or ion has and how they are arranged.

Electron shell

A region of an atom with a fixed energy that contains electrons orbiting the nucleus.

Electron shell repulsion theory.

The theory that in a molecule lone pair/lone pair bond angles are the biggest, lone pair/bonding pair bond angles are the second biggest and bonding pair/bonding pair bond angles are the smallest.

Electron shielding

When inner electrons effectively screen the outer electrons from the pull of the nucleus.

Electronegativity

The ability of an atom to attract the bonding electrons in a covalent bond.

Electrophile

An electron-pair acceptor.

Empirical formula

The formula giving the simplest whole number ratio of atoms to each element in a compound.

First ionisation energy

The energy needed to remove one mole of electrons from one mole of gaseous atoms.

General Formula

An algebraic formula that can describe any member of a homologous series of compounds

Giant Covalent Lattice

A structure consisting of a huge network of covalently bonded atoms. Also called a macromolecular structure.

Giant ionic lattice structure

A regular repeated structure made of oppositely charged ions strongly attracted to each other in all directions.

Giant metallic lattice structure

A regular structure consisting of closely packed positive metal ions in a sea of delocalised electrons.

Hydrated Salt

A salt that contains water of crystalisation.

Hydrocarbon

A molecule that only contains hydrogen and carbon atoms.

Hydrogen Bond

The strongest intermolecular force. It occurs when polarised covalent bonds cause hydrogen atoms to form weak bonds with lone pairs of electrons on fluorine, nitrogen or oxygen atoms of other molecules.

Indicator

A substance that changes colour at a certain pH.

Induced dipole-dipole interactions

A type of intermolecular force caused by temporary dipoles, which causes all atoms and molecules to be attracted to each other. Also called London (dispersion) forces.

Intermolecular forces

Forces between molecules e.g. induced dipole-dipole forces, permanent dipole-dipole forces and hydrogen bonding.

Ion

A charged particle formed when one or more electrons are lost or gained by an atom or molecule.

Ionic Bond

An electrostatic attraction between positive and negative ions.

Ionic Equation

An equation which only shows the reacting particles of a reaction involving ions.

Ionisation

The removal of one or more electrons from an atom or molecule, resulting in an ion forming.

Isotope

One of two or more forms of an element with the same number of protons but different numbers of neutrons and masses.

Isotopic Abundance

The relative amount of a particular isotope occurring in a sample of an element.

Lattice

A regular structure made up of atoms or ions.

Mass number

The total number of protons and neutrons in the nucleus of an atom.

Mass Spectrometry

An analytical technique used to find the structure of a molecule by measuring the masses of the ions it produces when it is bombarded with electrons.

Mass Spectrum

A chart produced by a mass spectrometer

Model

A simplified picture or representation of a real physical problem.

Molar mass

The mass of one mole of something.

Molar Ratio

The ratio of the number of moles of each reactant and product in a balanced chemical equation

Mole

The unit of amount of substance. One mole is roughly 6.02 x 10^23 particles (the Avagado constant).

Molecular Formula

A way of representing molecules that shows the actual number of atoms of each element in a molecule.

Molecular ion

An ion made up of a group of atoms with an overall charge.

Monomer

A small molecule which is used to make a polymer

Neutralisation Reaction

A reaction between an acid and a base to produce a salt and water

Neutron

A subatomic particle with a charge of 0 and a relative mass of 1, located in the nucleus of an atom.

Noble gas

An element in Group 0 of the periodic table.These elements are extremely stable because they have a full outer shell.

Nuclear model of the atom

A model for the structure of an atom proposed by Rutherford. He suggested that atoms consist of small positively charged nucleus, surrounded by a cloud of negatively charged electrons.

Nucleophile

An electron-pair donor

Nucleus

The central part of an atom or ion, made up of protons and neutrons.

Orbital

A region of a sub-shell that contains a maximum of two electrons with opposite spins.

Oxidation

Loss of electrons

Oxidation number

The total number of electrons an element has donated or accepted. Also called an oxidation state.

Oxidising agent

Something that accepts electrons and gets reduced.

Percentage Yield

The amount of product that is actually obtained during a reaction expressed as a percentage of the amount of product that should form.

Periodicity

The trends in physical and chemical properties of elements as you go across the periodic table.

Permanent dipole-dipole interactions

Intermolecular forced that exist because the difference in electronegativities in a polar bond causes weak electrostatic forces of attraction between molecules.

Plum pudding model

A model for the structure of an atom proposed by Thomson. He suggested that atoms consist of a positively charged sphere with negatively charged electrons embedded in them.

Polar bond

A covalent bond where a difference in electronegativity has caused a shift in electron density in the bond.

Polar molecule

A molecule containing polar bonds that are arranged so that dipoles do not cancel each other out, causing an overall dipole to be created across the molecule.

Polymer

A long molecule formed from lots of smaller molecules (monomers) joined together.

Proton

A subatomic particle with a relative charge of 1+ and a relative mass of 1, located in the nucleus of an atom.

Quantum model

The currently accepted model for the structure of an atom, where particles' positions are predicted by probabilities.

Radical

A particle with an unpaired electron.

Redox reaction

A reaction where reduction and oxidation happen simultaneously.

Reducing agent

Something that donates electrons and gets oxidised.

Reduction

Gain of electrons

Relative atomic mass

The average mass of an atom of an element compared to 1/12 of the mass of an atom of carbon-12.

Relative formula mass

The average mass of a molecule or formula unit compared to 1/12 of the mass of an atom of carbon-12

Relative isotopic mass

The mass of an atom of an isotope of an element compared to 1/12 of the mass of an atom of carbon-12.

Relative molecular mass

The average mass of a molecule compared to 1/12 of the mass of an atom of carbon-12.

Salt

A compound formed when the hydrogen in an acid molecule is replaced by a metal ion or ammonium ion.

Simple molecular structure

A compound with strong covalent bonds within its molecules but weak forces between its molecules

Skeletal Formula

A simplified organic formula which only shows the carbon skeleton and associated functional groups.

Spin

A type of momentum possessed by an electron. Spin can either be "down" or "up".

Standard conditions

100KPa pressure and a temperature of 298K.

Standard solution

A solution with a precisely known concentration.

Standard state

A substance's physical state under standard conditions.

State symbol

A symbol placed after a chemical in an equation that tell you what state of matter it is in.

Strong acid/base

An acid/base that almost completely ionises in an aqueous solution.

Structural Formula

A way of representing molecules that shows the atoms carbon by carbon with the attached hydrogens and functional groups.

Sub-shell

A sub-division of an energy-level (shell). Sub-shells may be s,p,d or f sub-shells.

Successive ionisation energy

The energy needed to remove 1 mole of each subsequent electron from each ion in 1 mole of positively charged gaseous ions.

Titration

A type of experiment used to find concentration of a solution. It involves gradually adding one solution to a known volume of another until the reaction between the two is complete.

Van der Waals forces

A term referring to both induced dipole-dipole interactions and permanent dipole-dipole interactions.

Water of crystalisation

The water contained in an ionic lattice.

Weak acid/base

An acid/base that only slightly ionises in an aqueous solution.

Yield

The amount of product you get from a reaction.

Enthalpy

A measure of heat energy in a chemical reaction.