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27 Cards in this Set

  • Front
  • Back

Lipids

Refers to a collection of organic molecules of varying chemical composition

Lipids

Are grouped together on the basis of their solubility in nonpolar solvents

Fatty acid


Glycerides


Nonglycide lipids


Complex lipids

4 main groups of lipids

Energy source


Energy storage


Cell membrane structural components


Hormones


Vitamins


Vitamin absorption


Protection


Insulation

Biological functions of lipids

Fatty acids

Are long-chain monocarboxylic acids Generally contain an even number of carbon atoms

Length of the carbon chains


Degree of unsaturation


Location of double bond

Classification of fatty acids

CH3(CH2)nCOOH

General formula of saturated fatty acids

Unsaturated fatty acids

Composed of at least one carbon-to-carbon double bond

MUFA


PUFA

Two types of unsaturated fatty acids

MUFA

Composed of one carbon-to-carbon double bond

PUFA

Composed of more than one carbon-to-carbon double bond

PUFA

are identified by position of the double bond nearest the methyl end (CH3) of the carbon chain; this is described as an omega number

Cis- fatty acids

H’s on same side of the double bond; fold into a U-like formation; naturally occurring

Trans- fatty acids

H’s on the opposite side of the double bond; occur in partially hydrogenated food

Esterification

Fatty acids react with alcohols to form esters and water

Acid hydrolysis

Producing fatty acids from esters


Opposite of esterification

Sapofication

Is the base-catalyzed hydrolysis of an ester the product of this reaction, an ionized salt, is a soap

Saponification

Is the base-catalyzed hydrolysis of an ester

Soap

Product of saponification is

Hydrogenation


Partial hydrogenation

Reaction at the Double Bond (Unsaturated Fatty Acids)

Hydrogenation

Used in the food industry to convert polyunsaturated vegetable oils into saturated solid fats

Partial hydrogenation

Carried out to add hydrogen to some, but not all, double bonds in polyunsaturated oils In this way liquid vegetable oils are converted into solid form (Crisco and margarine)

Long-chain, medium-chain, short-chain

Length of carbon chain

Saturated, Unsaturated (Mono, Poly)

Degree of unsaturation

Omega-3 Fatty Acid, Omega-6 Fatty Acid

Location of double bonds

Saturated fatty acids

Each C being “saturated” with H

Eicosopentaenoic acid (EPA)


Docosahexaenoic acid (DHA)


Alpha-linolenic acid (ALA)

Omega - 3